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Beilstein J. Org. Chem. 2018, 14, 1859–1870, doi:10.3762/bjoc.14.160
Graphical Abstract
Figure 1: Examples of reported SCS palladium(II) pincer complexes 1–13.
Figure 2: a) Reported SNS palladium(II) pincer complexes 14–16 as catalysts for Suzuki–Miyaura cross coupling ...
Scheme 1: Synthesis of pincer ligands 19a–d and complexes 17a–d.
Figure 3: Molecular structure of 17d. Selected bond distances (Å) and bond angles (°); S(1)–Pd(1)–Cl(1) 93.27...
Scheme 2: Proposed mechanism of the Suzuki–Miyaura coupling reaction using pincer complex 17d.
Figure 4: Energy profile for the oxidative addition reaction involving 4-bromoanisole and Pd(II) catalyst pre...
Scheme 3: Investigation on the reusability of the catalyst.
Figure 5: Reusability of pincer complex 17d as a catalyst for the Suzuki–Miyaura cross coupling reaction.
Scheme 4: Suzuki–Miyaura coupling reaction catalysed by the SN-bidentate complex 20a.